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β-to-β Singly linked subphthalocyanine dimers with effective π-conjugation

Identificadores del recurso

Organic Letters 26.44 (2024): 9471-9475

1523-7060 (print)

1523-7052 (online)

http://hdl.handle.net/10486/716127

10.1021/acs.orglett.4c03407

9471

9475

Procedència

(Biblos-e Archivo)

Fitxa

Títol:: β-to-β Singly linked subphthalocyanine dimers with effective π-conjugation
Tema:: Química
Descripció:: In this work, a series of π-conjugated Subphthalocyanine dimers assembled by simple π-bridges were efficiently synthesized through metal-catalyzed reactions. Despite being singly linked, these readily accessible arrays exhibit excellent π-electron communication, significantly perturbing the orbital distribution of conventional SubPcs and inducing notable alterations in their optical properties. The findings presented here demonstrate the potential of SubPcs for constructing curved porphyrin arrays with well-conjugated skeletons and intriguing functionalities; Financial support from the Spanish MCIN/AEI/10.13039/501100011033 and European Union NextGenerationEU/PRTR (PID2020-116490GB-I00, TED2021-131255B-C43), MCIU/AEI/10.13039/501100011033/FEDER, UE (PID2023-151167NB-I00), the Comunidad de Madrid and the Spanish State through the Recovery, Transformation and Resilience Plan [“Materiales Disruptivos Bidimensionales(2D)” (MAD2D-CM) (UAM1)-MRR Materiales Avanzados], and the European Union through the Next Generation EU funds is fully acknowledged. IMDEA Nanociencia acknowl-edges support from the “Severo Ochoa” Programme for Centres of Excellence in R&D (MINECO, Grant SEV2016-0686). T.T. also acknowledges the Alexander von Humboldt Foundation (Germany) for the A. v. Humboldt - J. C. Mutis Research Award 2023 (Ref 3.3 - 1231125 - ESP-GSA). M.G.-G. acknowledges MECD, Spain, for a F.P.U. Fellowship. We acknowledge the generous allocation of computer time at the Centro de Computación Científica at the Universidad Autónoma de Madrid (CCC-UAM)
Idioma:: English
Relació:: Gobierno de España. PID2020-116490GB-I00; Gobierno de España. TED2021-131255B-C43; Gobierno de España. PID2023-151167NB-I00
Autor/Productor:: Holgado Espejo, Daniel; Gómez Gómez, Marta; Labella Santodomingo, Jorge; Torres Cebada, Tomás
Editor:: American Chemical Society
Otros colaboradores/productores:: UAM. Departamento de Química Orgánica
Drets:: http://creativecommons.org/licenses/by/4.0/; open access
Data:: 2024-10-31
Tipo de recurso:: journal article; info:eu-repo/semantics/publishedVersion
Format:: application/pdf

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